B

解析試題分析：句意：---你能告訴我Mr Li什么時(shí)候到北京嗎？---當(dāng)然。當(dāng)他到達(dá)時(shí)，我會(huì)打電話給你。第一個(gè)when什么時(shí)候，根據(jù)情景得知應(yīng)用一般將來時(shí)。而第二個(gè)when意為當(dāng)……時(shí)候，應(yīng)用主將從現(xiàn)，從句用一般現(xiàn)在時(shí)表將來，故用arrives。故選B。
考點(diǎn)：考查時(shí)態(tài)的用法。

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